Source:http://linkedlifedata.com/resource/pubmed/id/18186621
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
5
|
| pubmed:dateCreated |
2008-1-31
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| pubmed:abstractText |
The hyper-Raman spectrum of buckminsterfullerene C60 was observed at room temperature. The spectrum clearly showed infrared-active modes with t(1u) symmetry and the silent modes with t(2u), g(u), and h(u) as a result of electronic resonances via the Herzberg-Teller mechanism. Moreover, Raman-active modes with a(g) and h(g) were also detected, although these were hyper-Raman-forbidden in the electric dipole approximation, suggesting a contribution of higher-order nonlinear processes such as magnetic dipole transitions. These results suggest that hyper-Raman spectroscopy and microscopy are indeed widely applicable in the field of molecular science.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Feb
|
| pubmed:issn |
1520-5215
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:day |
7
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| pubmed:volume |
112
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
790-3
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| pubmed:year |
2008
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| pubmed:articleTitle |
Resonance hyper-Raman scattering of fullerene C60 microcrystals.
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| pubmed:publicationType |
Letter
|