Linked Life Data

18185862

Source:http://linkedlifedata.com/resource/pubmed/id/18185862

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
4
pubmed:dateCreated
2008-1-10
pubmed:abstractText
Two new compounds constructed from tetra-Ni-substituted sandwich-type polyoxometalates functionalized by organic groups, (NH(4))(2)[Ni(4)(enMe)(8)(H(2)O)(2)Ni(4)(enMe)(2)(PW(9)O(34))(2)].9H(2)O (enMe = 1,2-diaminopropane) (1) and Na(2)[H(6)N(2)(CH(2))(6)](2){Ni(4)[H(4)N(2)(CH(2))(6)](2)(H(2)PW(9)O(34))(2)}.7H(2)O (2), have been successfully synthesized under hydrothermal conditions. Single-crystal X-ray diffraction analysis is carried out on these two compounds (1 and 2), which both crystallize in the triclinic system. Compound 1 represents the first example of a 2D layer structure consisting of the sandwich-type polyoxoanions with six supporting [Ni(enMe)(2)](2+) moities and two organic functionalized groups. Compound 2 exhibits a 1D chain-like structure based on sandwich-type polyoxoanions and sodium cations, which are further connected into a 2D layer structure via hydrogen-bonding interactions between the 1,6-hexanediamine molecules and the sandwich-type [Ni(4)(H(4)N(2)(CH(2))(6))(2)(H(2)PW(9)O(34))(2)](6-) polyoxoanions. A magnetic study of the two compounds indicates that intramolecular ferromagnetic Ni-Ni interactions exist in the tetranuclear metal cluster.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jan
pubmed:issn
1477-9226
pubmed:author
pubmed:issnType
Print
pubmed:day
28
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
463-8
pubmed:meshHeading
pubmed:year
2008
pubmed:articleTitle
Two extended structures constructed from sandwich-type polyoxometalates functionalized by organic amines.
pubmed:affiliation
Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, P. R. China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't