Source:http://linkedlifedata.com/resource/pubmed/id/18179167
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
4
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| pubmed:dateCreated |
2008-2-11
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| pubmed:abstractText |
Reduction of [P 2N 2]ZrCl 2 (where P 2N 2 = PhP(CH 2SiMe 2NSiMe 2CH 2) 2PPh) by KC 8 under N 2 generates the dinuclear dinitrogen complex ([P 2N 2]Zr) 2(mu-eta (2):eta (2)-N 2) and impurities in varying yields depending on the solvent and temperature. The toluene complex [P 2N 2]Zr(eta (6)-C 7H 8) along with a dinuclear species with bridging PC 6H 5 groups is observable. Also observable in the crude reaction mixtures is the mu-oxodiazenido derivative, ([P 2N 2]Zr) 2(mu-eta (2):eta (2)-N 2H 2)(mu-O), due to reaction with trace H 2O. This paper reports the full details of the preparation of ([P 2N 2]Zr) 2(mu-eta (2):eta (2)-N 2) including an improved method that involves reduction at low temperatures in a tetrahydrofuran solvent. Also reported is a reproducible synthesis of the oxodiazenido complex along with the X-ray structures of the dinitrogen complex and the oxodiazenido derivative.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Feb
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| pubmed:issn |
0020-1669
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
18
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| pubmed:volume |
47
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
1319-23
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| pubmed:year |
2008
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| pubmed:articleTitle |
Side-on bound dinitrogen complex of zirconium supported by a P2N2 macrocyclic ligand.
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| pubmed:affiliation |
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, Canada.
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| pubmed:publicationType |
Journal Article
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