Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
2007-12-25
pubmed:abstractText
Chelate-assisted phytoextraction has been proposed as a potential tool for phytoremediation of U contaminated sites. In this context, the effects of five biodegradable amendments on U release in contaminated soils were evaluated. Three soils were involved in this study, one with a relatively high background level of U, and two which were contaminated with U from industrial effluents. Soils were treated with 5 mmol kg(-1) dry weight of either citric acid, NH(4)-citrate/citric acid, oxalic acid, S,S-ethylenediamine disuccinic acid or nitrilotriacetic acid. Soil solution concentration of U was monitored during 2 weeks. All amendments increased U concentration in soil solution, but citric acid and NH(4)-citrate/citric acid mixture were most effective, with up to 479-fold increase. For oxalic acid, S,S-ethylenediamine disuccinic acid and nitrilotriacetic acid, the increase ranged from 10-to 100-fold. The highest concentrations were observed 1 to 7 days after treatment, after which U levels in soil solution gradually decreased. All amendments induced a temporary increase of soil solution pH and TOC that could not be correlated with the release of U in the soil solution. Thermodynamic stability constants (log K) of complexes did not predict the relative efficiency of the selected biodegradable amendments on U release in soil solution. Amendments efficiency was better predicted by the relative affinity of the chelate for Fe compared to U.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Feb
pubmed:issn
0048-9697
pubmed:author
pubmed:issnType
Print
pubmed:day
25
pubmed:volume
391
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
26-33
pubmed:meshHeading
pubmed:year
2008
pubmed:articleTitle
Effect of biodegradable amendments on uranium solubility in contaminated soils.
pubmed:affiliation
Belgian Nuclear Research Centre, Environment Health and Safety, Biosphere Impact Studies, Boeretang 200, 2400 Mol, Belgium.
pubmed:publicationType
Journal Article