Linked Life Data

18028611

Source:http://linkedlifedata.com/resource/pubmed/id/18028611

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
9
pubmed:dateCreated
2007-11-21
pubmed:abstractText
Transmittance Fourier transform infrared (FT-IR) spectra of liquid water in the 4-80 degrees C temperature range are reported in the whole mid-infrared (MIR) region (4000-360 cm (-1)). The spectra were recorded by using a newly developed, home-made transmittance cell, working in light vacuum conditions (pressures of the order of 3-4 millibar). This permits the elimination of the aqueous vapor bands from the liquid spectra, particularly in the bending region, and the rapid collection of data without fluxing large amounts of nitrogen through the interferometer sample chamber. The temperature evolution of the OH stretching and HOH deformation bands is discussed in terms of Gaussian components analysis and a two-state model describing the equilibrium between different H-bond structures of liquid water. From this picture, structural and thermodynamic information about the hydrogen-bonding network of water is obtained.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Sep
pubmed:issn
0003-7028
pubmed:author
pubmed:issnType
Print
pubmed:volume
59
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1155-9
pubmed:year
2005
pubmed:articleTitle
Transmittance Fourier transform infrared spectra of liquid water in the whole mid-infrared region: temperature dependence and structural analysis.
pubmed:affiliation
Dipartimento di Fisica, Università di Perugia, Via A. Pascoli, I-06100 Perugia, Italy.
pubmed:publicationType
Journal Article