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rdf:type | |
lifeskim:mentions | |
pubmed:dateCreated |
1992-4-28
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pubmed:abstractText |
The 1H-n.m.r. spectra of the Streptococcus pneumoniae type 9V (S68 in American nomenclature) capsular polysaccharide (PS) and its O-deacetylated derivative [which is structurally identical to the S. pneumoniae type 9A (S33) PS] were assigned using COSY, relayed-COSY, and 2D-NOESY experiments. The positions of the OAc groups in the alpha-GlcA, beta-ManNAc, and alpha-Glc residues of the native 9V PS were established using 2D-n.m.r. and chemical shift arguments, and the relative proportions of different O-acetylated species were estimated by integration of well-resolved 1H-n.m.r. signals. The locations of the OAc substituents differ from those previously reported. [formula: see text].
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Bacterial Capsules,
http://linkedlifedata.com/resource/pubmed/chemical/Galactose,
http://linkedlifedata.com/resource/pubmed/chemical/Glucose,
http://linkedlifedata.com/resource/pubmed/chemical/Hexosamines,
http://linkedlifedata.com/resource/pubmed/chemical/Polysaccharides, Bacterial,
http://linkedlifedata.com/resource/pubmed/chemical/mannosamine
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pubmed:status |
MEDLINE
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pubmed:month |
Sep
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pubmed:issn |
0008-6215
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
30
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pubmed:volume |
218
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
175-84
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pubmed:dateRevised |
2006-11-15
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pubmed:meshHeading |
pubmed-meshheading:1802383-Acetylation,
pubmed-meshheading:1802383-Bacterial Capsules,
pubmed-meshheading:1802383-Carbohydrate Sequence,
pubmed-meshheading:1802383-Galactose,
pubmed-meshheading:1802383-Glucose,
pubmed-meshheading:1802383-Hexosamines,
pubmed-meshheading:1802383-Magnetic Resonance Spectroscopy,
pubmed-meshheading:1802383-Molecular Sequence Data,
pubmed-meshheading:1802383-Polysaccharides, Bacterial,
pubmed-meshheading:1802383-Streptococcus pneumoniae
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pubmed:year |
1991
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pubmed:articleTitle |
Location and quantitation of the sites of O-acetylation on the capsular polysaccharide from Streptococcus pneumoniae type 9V by 1H-n.m.r. spectroscopy: comparison with type 9A.
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pubmed:affiliation |
Chemistry Division, National Institute for Biological Standards & Control, Hertfordshire, Great Britain.
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pubmed:publicationType |
Journal Article,
Comparative Study,
Research Support, Non-U.S. Gov't
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