Source:http://linkedlifedata.com/resource/pubmed/id/18007495
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
11
|
| pubmed:dateCreated |
2007-11-16
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| pubmed:abstractText |
Two mononuclear complexes, [Ni(acac)2].0.5CH3OH (1) and[Co(acac)2NO3].2H2O (2) (acac = pentane-2,4-dione), have been synthesized and characterized by single crystal X-ray analysis. Complex 1 crystallizes in the monoclinic space group P2(1)/c with a = 9.295(4), b = 11.450(5), c = 12.974(6) A, V = 1379.1(11) A(3),beta = 92.854(7), and Z = 4. Complex 2 crystallizes in the triclinic space group P(-1) with a= 8.153(9), b = 9.925(11), c = 10.355(12), V = 746.3(15) A(3), alpha = 70.530(16), beta =71.154(15), gamma = 80.698(16) and Z = 2. Complex 1 has a one-dimensional chain-like structure, which is extended by weak hydrogen contacts, while complex 2 shows a three-dimensional network structure.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:citationSubset |
IM
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| pubmed:chemical | |
| pubmed:status |
MEDLINE
|
| pubmed:issn |
1420-3049
|
| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:volume |
9
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
949-56
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| pubmed:dateRevised |
2009-10-27
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| pubmed:meshHeading |
pubmed-meshheading:18007495-Cobalt,
pubmed-meshheading:18007495-Crystallography, X-Ray,
pubmed-meshheading:18007495-Hydrogen Bonding,
pubmed-meshheading:18007495-Molecular Conformation,
pubmed-meshheading:18007495-Molecular Structure,
pubmed-meshheading:18007495-Nickel,
pubmed-meshheading:18007495-Organometallic Compounds,
pubmed-meshheading:18007495-Pentanes
|
| pubmed:year |
2004
|
| pubmed:articleTitle |
Synthesis and characterization of the complexes of pentane-2,4-dione with nickel(II) and cobalt(III): [Ni(acac)2].0.5CH3OH and [Co(acac)2NO3].2H2O (acac = pentane-2,4-dione).
|
| pubmed:affiliation |
Department of Chemistry, Fuyang Normal College, Fuyang Anhui 236041, PR China.
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| pubmed:publicationType |
Journal Article
|