Linked Life Data

18007360

Source:http://linkedlifedata.com/resource/pubmed/id/18007360

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
8
pubmed:dateCreated
2007-11-16
pubmed:abstractText
A new iso-amyl benzothiazolyl sulfoxide (ABSO) was synthesized and used in the extraction of Pd(II) from hydrochloric acid media. Pd(II) was extracted quantitatively from 0.1 M HCl with ABSO in benzene (0.5 M). Ammonia solution (2.0 M) could be used as stripping agent. ABSO and Pd(II) form a 2:1 adduct [Pd (ABSO)2Cl2] in the extraction. X-ray crystal structure determination revealed PdCl2(ABSO)2 is a square-planar complex in which ABSO acts as a neutral unidentate ligand coordinated with palladium(II) via the thiazolyl N atom.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:issn
1420-3049
pubmed:author
pubmed:issnType
Electronic
pubmed:volume
10
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
912-21
pubmed:dateRevised
2009-10-27
pubmed:meshHeading
pubmed:year
2005
pubmed:articleTitle
A new iso-amyl benzothiazolyl sulfoxide as an extractant for palladium and the crystal structure of its palladium (II) complex.
pubmed:affiliation
Department of Applied Chemistry, South China University of Technology, Guangzhou 510640, PR China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't