Linked Life Data

18007333

Source:http://linkedlifedata.com/resource/pubmed/id/18007333

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
6
pubmed:dateCreated
2007-11-16
pubmed:abstractText
The synthesis, spectroscopic characterization and X-ray crystal structure of a new chiral triosmium alkylidyne carbonyl cluster, (R,S)-[Os3(mu-H)2(CO)9{mu3-CPPh2(eta(5)-C5H4)Fe(eta(5)-C5H3(PPh2)CH(Me)NM(2)}] (1) are described. Compound 1 crystallizes in the non-centrosymmetric space group P2(1) and its absolute configuration has been established.The structure consists of an Os3C metal core with one of the PPh2 moieties of the chiral ferrocenylphosphine bonded to the apical alkylidyne carbon atom to give a zwitterionic cluster complex, reminiscent of the phosphorus ylide.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:issn
1420-3049
pubmed:author
pubmed:issnType
Electronic
pubmed:volume
10
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
640-8
pubmed:dateRevised
2009-10-27
pubmed:meshHeading
pubmed:year
2005
pubmed:articleTitle
Synthesis and crystal structure of a new triosmium alkylidyne carbonyl cluster containing a chiral ferrocenylphosphine ligand.
pubmed:affiliation
Department of Chemistry, Hong Kong Baptist University, Waterloo Road, Kowloon Tong, Hong Kong, PR China. rwywong@hkbu.edu.hk
pubmed:publicationType
Journal Article