Source:http://linkedlifedata.com/resource/pubmed/id/17989462
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 11
|
| pubmed:dateCreated |
2007-11-8
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| pubmed:abstractText |
The title salt, bis[2,3-bis(aminocarbonyl)-8,9-bis(methylsulfanyl)tetrathiafulvalenium] di-mu-bromido-bis[bromidocopper(II)], (C(10)H(10)N(2)O(2)S(6))(2)[Cu(2)Br(4)], contains 2,3-bis(aminocarbonyl)-8,9-bis(methylsulfanyl)tetrathiafulvalenium radical cations, [DMT-TTF(CONH(2))(2)](.+), and [Cu(2)Br(4)](2-) anions. The cations are associated across centres of inversion in a head-to-tail fashion via short face-to-face S...S stacking (TTF moiety). These dimers are further assembled into a one-dimensional chain structure via interdimer double S...S contacts involving the methylsulfanyl groups. The one-dimensional chains give rise to a two-dimensional structure through intermolecular double N-H...O hydrogen bonds involving the amide group. The [Cu(2)Br(4)](2-) anions, which straddle centres of inversion, are located between the cation layers. Electron paramagnetic resonance measurements show a radical signal, indicating that the two TTF(.+) radicals are not completely coupled in the dimer.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Nov
|
| pubmed:issn |
1600-5759
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
63
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m496-8
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| pubmed:year |
2007
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| pubmed:articleTitle |
A new tetrathiafulvalene-diamide cation salt with [Cu2Br4]2- anions.
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| pubmed:affiliation |
Department of Chemistry, Suzhou University, Suzhou 215123, People's Republic of China.
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| pubmed:publicationType |
Journal Article
|