Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
2
pubmed:dateCreated
2007-11-23
pubmed:abstractText
The current study offers a first insight into the interfacial properties of pullulan-sodium dodecyl sulphate (SDS) aqueous two-phase systems (ATPS) in the presence of sodium chloride (NaCl). The effect of composition on the interfacial tension (sigma) in these ATPS was investigated over a wide range of pullulan, SDS and NaCl concentrations. An increase in the interfacial tension was observed with increasing pullulan and SDS concentrations and a small increase was also observed as the NaCl concentration was increased. In both cases the interfacial tension increases were closely related to the phase behaviour of these systems; as a consequence of increasing the pullulan, SDS and/or NaCl concentrations, the system moves further away from the critical point. In all systems interfacial tensions (of the order of muN/m) were comparable with those reported for polymer-polymer ATPS. Interfacial tensions sigma can be well correlated with the difference in pullulan and SDS concentrations between the phases (DeltaC pul and DeltaC SDS) and also the tie-line length (TLL); all yield straight lines on a log-log scale.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jan
pubmed:issn
0021-9797
pubmed:author
pubmed:issnType
Print
pubmed:day
15
pubmed:volume
317
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
604-10
pubmed:dateRevised
2009-11-11
pubmed:meshHeading
pubmed:year
2008
pubmed:articleTitle
Interfacial tension in aqueous biopolymer-surfactant mixtures.
pubmed:affiliation
Centre for Formulation Engineering, Department of Chemical Engineering, University of Birmingham, Birmingham, Edgbaston, B15 2TT, UK. f.spyropoulos@bham.ac.uk
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't