Source:http://linkedlifedata.com/resource/pubmed/id/17914837
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
22
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| pubmed:dateCreated |
2007-10-18
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| pubmed:abstractText |
Cationic palladium(II) ([Pd(MeCN)4](BF4)2) provides the first transition-metal-catalyzed method for electrophilic activation of electron-deficient 1,1-difluoro-1-alkenes, which allows their Friedel-Crafts-type cyclization with an intramolecular aryl group via a Wacker-type process. By using BF3.OEt2, the cyclization was effected by a catalytic amount of the palladium without its reoxidation.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Oct
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| pubmed:issn |
1523-7060
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
25
|
| pubmed:volume |
9
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
4639-42
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| pubmed:year |
2007
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| pubmed:articleTitle |
Activation of 1,1-difluoro-1-alkenes with a transition-metal complex: palladium(II)-catalyzed Friedel-Crafts-type cyclization of 4,4-(difluorohomoallyl)arenes.
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| pubmed:affiliation |
Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan.
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| pubmed:publicationType |
Journal Article
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