Linked Life Data

17904893

Source:http://linkedlifedata.com/resource/pubmed/id/17904893

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3
pubmed:dateCreated
2008-6-10
pubmed:abstractText
The sharp-line absorption spectrum of cis-beta-[CrCl(2)(2,2,3-tet)]ClO(4) (2,2,3-tet: 1,4,7,11-tetraazaundecane) has been measured between 13,000 and 16,000 cm(-1) at 5K. The 77K emission, 298 K infrared and visible spectra have also been measured. The zero-phonon band in the highly resolved absorption spectrum splits into four components. The vibrational intervals of the electronic ground state were determined from the far-infrared and emission spectra. The 10 electronic bands due to spin-allowed and spin-forbidden transitions were assigned. Using the observed transitions, a ligand field analysis has been performed to probe the ligand field properties of coordinated atoms in the title chromium(III) complex. The X-ray crystal structure at low-temperature was determined to help in assigning the sharp-line electronic transitions.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Aug
pubmed:issn
1386-1425
pubmed:author
pubmed:issnType
Print
pubmed:volume
70
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
619-25
pubmed:meshHeading
pubmed:year
2008
pubmed:articleTitle
Electronic and vibrational spectroscopy of cis-beta-[CrCl(2)(1,4,7,11-tetrazaundecane)chromium(III) perchlorate.
pubmed:affiliation
Department of Chemistry, Andong National University, Andong 760-749, South Korea. jhchoi@andong.ac.kr
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't