Linked Life Data

17896047

Source:http://linkedlifedata.com/resource/pubmed/id/17896047

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
38
pubmed:dateCreated
2007-9-26
pubmed:abstractText
Reaction of a phosphinobenzylsilane compound with ruthenium complexes leads to C-H and/or Si-H activation. The new complex Ru{eta(2)-H-SiMe2CH(o-C(6)H(4))PPh2}2 (5) was isolated and X-ray, NMR and DFT studies reveal that 5 displays two agostic Si-H interactions and two carbon-metallated bonds.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Oct
pubmed:issn
1359-7345
pubmed:author
pubmed:issnType
Print
pubmed:day
14
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
3963-5
pubmed:year
2007
pubmed:articleTitle
Agostic Si-H bond coordination assists C-H bond activation at ruthenium in bis(phosphinobenzylsilane) complexes.
pubmed:affiliation
Centro de Investigaciones Químicas, Cuernavaca, Morelos, México, Av. Universidad 1001, Col. Chamilpa, Mexico. vmontielp@ciq.uaem.mx
pubmed:publicationType
Journal Article