Source:http://linkedlifedata.com/resource/pubmed/id/17887832
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
11
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| pubmed:dateCreated |
2007-9-24
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| pubmed:abstractText |
Ti- and V-bz2 (bz=C6H6) sandwich complexes have been prepared in a laser-ablation cluster beam source and studied by pulsed field ionization-zero electron kinetic energy photoelectron spectroscopy and theoretical calculations. The ground electronic states of the neutral Ti- and V-bz2 complexes are determined to be 1A1g and 2A1g, and their ionization energies are measured to be 5.732+/-0.001 and 5.784+/-0.002 eV, respectively. These neutral complexes have eta6 binding and are in an eclipsed D6h configuration with flat benzene rings. Ionization of the 1A1g and 2A1g neutral states of Ti- and V-bz2 yields the 2B1g and 3B1g ion states, respectively, in a D2h point group with slightly puckered benzene rings. In addition, the binding and structures of these two complexes are compared with other first-row transition metal bis(benzene) sandwiches.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Sep
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| pubmed:issn |
0021-9606
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
21
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| pubmed:volume |
127
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
114302
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| pubmed:year |
2007
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| pubmed:articleTitle |
Electronic states of neutral and cationic bis(benzene) titanium and vanadium sandwich complexes studied by pulsed field ionization electron spectroscopy.
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| pubmed:affiliation |
Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055, USA.
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| pubmed:publicationType |
Journal Article
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