Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
4
pubmed:dateCreated
2008-2-25
pubmed:abstractText
The synthesis of MCM-22 zeolite under hydrothermal crystallization conditions has been performed by an ultrasonic-assisted aging procedure. The ultrasonic-assisted aging of the initial aluminosilicate gel can shorten the crystallization time of MCM-22, decrease the amount of hexamethyleneimine (HMI) used, and broaden the range of SiO(2)/Al(2)O(3) ratios. By using the ultrasonic aging, pure phase of high-silica MCM-22 products with SiO(2)/Al(2)O(3)>100 can be obtained. When SiO(2)/Al(2)O(3) <or= 50, high crystalline MCM-22 zeolites with the reduced average crystal sizes can be made even with low HMI/SiO(2) ratio of 0.05 under static crystallization conditions. The acoustic cavitation of the ultrasonic is believed to be responsible for these positive results due to its cracking the crystal seeds and improving the solubility of silicate species.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Apr
pubmed:issn
1350-4177
pubmed:author
pubmed:issnType
Print
pubmed:volume
15
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
334-8
pubmed:dateRevised
2009-11-19
pubmed:meshHeading
pubmed:year
2008
pubmed:articleTitle
Synthesis of MCM-22 zeolite by an ultrasonic-assisted aging procedure.
pubmed:affiliation
Institute of New Catalytic Materials Science, College of Chemistry, Nankai University, Tianjin 300071, PR China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't