Source:http://linkedlifedata.com/resource/pubmed/id/17826901
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
3
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pubmed:dateCreated |
2008-3-17
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pubmed:abstractText |
A simple method for preparing highly daylight-induced photoactive nanocrystalline C,N,S-tridoped TiO2 powders was developed by a solid-phase reaction. The as-prepared TiO2 powders were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectra, N2 adsorption-desorption measurements and transmission electron microscopy (TEM). The photocatalytic activity was evaluated by the photocatalytic oxidation of formaldehyde under daylight irradiation in air. The results show that daylight-induced photocatalytic activities of the as-prepared TiO2 powders were improved by C,N,S-tridoping. The C,N,S-tridoped TiO2 powders exhibited stronger absorption in the near UV and visible-light region with red shift in the band-gap transition. When the molar ratio of CS(NH2)2 to xerogel TiO2 powders (prepared by hydrolysis of Ti(OC4H9)4 in distilled water) (R) was kept in 3, the daylight-induced photocatalytic activities of the as-prepared C,N,S-tridoped TiO2 powders were about more than six times greater than that of Degussa P25 and un-doped TiO2 powders. The high activities of the C,N,S-tridoped TiO2 can be attributed to the results of the synergetic effects of strong absorption in the near UV and visible-light region, red shift in adsorption edge and two phase structures of un-doped TiO2 and C,N,S-tridoped TiO2.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Apr
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pubmed:issn |
0304-3894
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
15
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pubmed:volume |
152
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1229-36
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pubmed:meshHeading |
pubmed-meshheading:17826901-Catalysis,
pubmed-meshheading:17826901-Microscopy, Electron, Transmission,
pubmed-meshheading:17826901-Photochemistry,
pubmed-meshheading:17826901-Powders,
pubmed-meshheading:17826901-Spectrophotometry, Ultraviolet,
pubmed-meshheading:17826901-Titanium,
pubmed-meshheading:17826901-X-Ray Diffraction
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pubmed:year |
2008
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pubmed:articleTitle |
Preparation and enhanced daylight-induced photocatalytic activity of C,N,S-tridoped titanium dioxide powders.
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pubmed:affiliation |
Yunyang Medical College, Shiyan 442000, Hubei, PR China.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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