Source:http://linkedlifedata.com/resource/pubmed/id/17791822
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
3635
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| pubmed:dateCreated |
2010-6-7
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| pubmed:abstractText |
The synthetic molecular oxygen carrier O(2)lrCl(CO)(P[C(6)H(5)](3))(2), discovered by Vaska, has been characterized in a complete molecular structure determination. The structure surmised by Vaska from spectroscopic data has been confirmed and, in addition, definitive details on the attachment of molecular oxygen to iridium in this 1 : 1 reversible oxygen carrier have been obtained. The two oxygen atoms are equidistant from the metal atom, as in Griffith's model of the oxygen atoms in oxyhemoglobin. The O-O bond length of 1.30 +/- 0.03 A is intermediate between those characteristic of O(2) (1.20 A) and O(2)(-2) (1.48 A), and corresponds closely to O(2)(-)(1.28 A).
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Aug
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| pubmed:issn |
0036-8075
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
28
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| pubmed:volume |
145
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
920-1
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| pubmed:year |
1964
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| pubmed:articleTitle |
Molecular Structure of the Synthetic Molecular Oxygen Carrier O2IrCl(CO)(P[C6H5]3)2.
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| pubmed:publicationType |
Journal Article
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