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pubmed-article:17728892pubmed:abstractTextFluorine-metal exchange reaction of 2,3,4,4,4-pentafluorocrotonates with organocuprate derived from Grignard reagent and CuCN takes place efficiently to generate the beta-metallated tetrafluorocrotonate intermediate, which reacts with various electrophiles to give beta-substituted 2,4,4,4-tetrafluorocrotonates.lld:pubmed
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pubmed-article:17728892pubmed:authorpubmed-author:IshiharaTakas...lld:pubmed
pubmed-article:17728892pubmed:authorpubmed-author:KonnoTsutomuTlld:pubmed
pubmed-article:17728892pubmed:authorpubmed-author:TakahashiTosh...lld:pubmed
pubmed-article:17728892pubmed:authorpubmed-author:YamadaShigeyu...lld:pubmed
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pubmed-article:17728892pubmed:pagination3679-81lld:pubmed
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pubmed-article:17728892pubmed:articleTitleA novel fluorine-metal exchange reaction of pentafluorocrotonate with organocuprate. Generation of beta-metallated tetrafluorocrotonate and its cross-coupling reaction.lld:pubmed
pubmed-article:17728892pubmed:affiliationDepartment of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Kyoto 606-8585, Japan.lld:pubmed
pubmed-article:17728892pubmed:publicationTypeJournal Articlelld:pubmed