17728892

Source:http://linkedlifedata.com/resource/pubmed/id/17728892

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0079411, umls-concept:C0205314, umls-concept:C0443286, umls-concept:C0678640, umls-concept:C0679622
pubmed:issue	35
pubmed:dateCreated	2007-8-30
pubmed:abstractText	Fluorine-metal exchange reaction of 2,3,4,4,4-pentafluorocrotonates with organocuprate derived from Grignard reagent and CuCN takes place efficiently to generate the beta-metallated tetrafluorocrotonate intermediate, which reacts with various electrophiles to give beta-substituted 2,4,4,4-tetrafluorocrotonates.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/9610838
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Sep
pubmed:issn	1359-7345
pubmed:author	pubmed-author:IshiharaTakashiT, pubmed-author:KonnoTsutomuT, pubmed-author:TakahashiToshioT, pubmed-author:YamadaShigeyukiS
pubmed:issnType	Print
pubmed:day	21
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	3679-81
pubmed:year	2007
pubmed:articleTitle	A novel fluorine-metal exchange reaction of pentafluorocrotonate with organocuprate. Generation of beta-metallated tetrafluorocrotonate and its cross-coupling reaction.
pubmed:affiliation	Department of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Kyoto 606-8585, Japan.
pubmed:publicationType	Journal Article