| pubmed-article:17720619 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:17720619 | lifeskim:mentions | umls-concept:C0039946 | lld:lifeskim |
| pubmed-article:17720619 | lifeskim:mentions | umls-concept:C0733755 | lld:lifeskim |
| pubmed-article:17720619 | lifeskim:mentions | umls-concept:C1441547 | lld:lifeskim |
| pubmed-article:17720619 | lifeskim:mentions | umls-concept:C1883073 | lld:lifeskim |
| pubmed-article:17720619 | lifeskim:mentions | umls-concept:C0332256 | lld:lifeskim |
| pubmed-article:17720619 | lifeskim:mentions | umls-concept:C0678594 | lld:lifeskim |
| pubmed-article:17720619 | lifeskim:mentions | umls-concept:C2603343 | lld:lifeskim |
| pubmed-article:17720619 | lifeskim:mentions | umls-concept:C1260969 | lld:lifeskim |
| pubmed-article:17720619 | lifeskim:mentions | umls-concept:C0073971 | lld:lifeskim |
| pubmed-article:17720619 | lifeskim:mentions | umls-concept:C2000611 | lld:lifeskim |
| pubmed-article:17720619 | pubmed:issue | 1 | lld:pubmed |
| pubmed-article:17720619 | pubmed:dateCreated | 2008-5-6 | lld:pubmed |
| pubmed-article:17720619 | pubmed:abstractText | Mononuclear and binuclear copper(II) complexes (1-8) with two ONS donor thiosemicarbazone ligands {salicylaldehyde 3-hexamethyleneiminyl thiosemicarbazone [H2L1] and salicylaldehyde 3-tetramethyleneiminyl thiosemicarbazone [H2L2]} have been prepared and physico-chemically characterized. IR, electronic and EPR spectra of the complexes have been obtained. The thiosemicarbazones bind to metal as dianionic ONS donor ligands in all the complexes except in [Cu(HL1)2] (2) and [Cu(HL2)2] (6). In compounds 2 and 6 the ligands are coordinated as monoanionic HL- ones. The magnetic susceptibility measurements indicate that all the complexes are paramagnetic. In complex [(CuL1)2] (1), the magnetic moment value is lower than the expected spin only value. In all the complexes g(||)>g( perpendicular)>2.0023 and G values within the range 2.5-3.5 are consistent with dx2-y2 ground state. The complexes were given the formula as [(CuL1)2] (1); [Cu(HL1)2] (2); [CuL1bpy] (3); [CuL1phen] (4); [CuL1gamma-pic].2H2O (5); [Cu(HL2)2] (6); [CuL2py].3H2O (7); [CuL2bipy] (8). The structure of the compound 8 have been solved by single crystal X-ray crystallography and was found to be distorted square pyramid around copper(II) ion. | lld:pubmed |
| pubmed-article:17720619 | pubmed:language | eng | lld:pubmed |
| pubmed-article:17720619 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:17720619 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:17720619 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:17720619 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:17720619 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:17720619 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:17720619 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:17720619 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:17720619 | pubmed:month | Jun | lld:pubmed |
| pubmed-article:17720619 | pubmed:issn | 1386-1425 | lld:pubmed |
| pubmed-article:17720619 | pubmed:author | pubmed-author:KurupMaliyeck... | lld:pubmed |
| pubmed-article:17720619 | pubmed:author | pubmed-author:LatheefLejiL | lld:pubmed |
| pubmed-article:17720619 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:17720619 | pubmed:volume | 70 | lld:pubmed |
| pubmed-article:17720619 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:17720619 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:17720619 | pubmed:pagination | 86-93 | lld:pubmed |
| pubmed-article:17720619 | pubmed:meshHeading | pubmed-meshheading:17720619... | lld:pubmed |
| pubmed-article:17720619 | pubmed:meshHeading | pubmed-meshheading:17720619... | lld:pubmed |
| pubmed-article:17720619 | pubmed:meshHeading | pubmed-meshheading:17720619... | lld:pubmed |
| pubmed-article:17720619 | pubmed:meshHeading | pubmed-meshheading:17720619... | lld:pubmed |
| pubmed-article:17720619 | pubmed:meshHeading | pubmed-meshheading:17720619... | lld:pubmed |
| pubmed-article:17720619 | pubmed:meshHeading | pubmed-meshheading:17720619... | lld:pubmed |
| pubmed-article:17720619 | pubmed:meshHeading | pubmed-meshheading:17720619... | lld:pubmed |
| pubmed-article:17720619 | pubmed:meshHeading | pubmed-meshheading:17720619... | lld:pubmed |
| pubmed-article:17720619 | pubmed:meshHeading | pubmed-meshheading:17720619... | lld:pubmed |
| pubmed-article:17720619 | pubmed:year | 2008 | lld:pubmed |
| pubmed-article:17720619 | pubmed:articleTitle | Spectral and structural studies of copper(II) complexes of thiosemicarbazones derived from salicylaldehyde and containing ring incorporated at N(4)-position. | lld:pubmed |
| pubmed-article:17720619 | pubmed:affiliation | Department of Applied Chemistry, Cochin University of Science and Technology, Kochi 682022, Kerala, India. | lld:pubmed |
| pubmed-article:17720619 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:17720619 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |
