Source:http://linkedlifedata.com/resource/pubmed/id/17720619
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
1
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pubmed:dateCreated |
2008-5-6
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pubmed:abstractText |
Mononuclear and binuclear copper(II) complexes (1-8) with two ONS donor thiosemicarbazone ligands {salicylaldehyde 3-hexamethyleneiminyl thiosemicarbazone [H2L1] and salicylaldehyde 3-tetramethyleneiminyl thiosemicarbazone [H2L2]} have been prepared and physico-chemically characterized. IR, electronic and EPR spectra of the complexes have been obtained. The thiosemicarbazones bind to metal as dianionic ONS donor ligands in all the complexes except in [Cu(HL1)2] (2) and [Cu(HL2)2] (6). In compounds 2 and 6 the ligands are coordinated as monoanionic HL- ones. The magnetic susceptibility measurements indicate that all the complexes are paramagnetic. In complex [(CuL1)2] (1), the magnetic moment value is lower than the expected spin only value. In all the complexes g(||)>g( perpendicular)>2.0023 and G values within the range 2.5-3.5 are consistent with dx2-y2 ground state. The complexes were given the formula as [(CuL1)2] (1); [Cu(HL1)2] (2); [CuL1bpy] (3); [CuL1phen] (4); [CuL1gamma-pic].2H2O (5); [Cu(HL2)2] (6); [CuL2py].3H2O (7); [CuL2bipy] (8). The structure of the compound 8 have been solved by single crystal X-ray crystallography and was found to be distorted square pyramid around copper(II) ion.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Aldehydes,
http://linkedlifedata.com/resource/pubmed/chemical/Copper,
http://linkedlifedata.com/resource/pubmed/chemical/Ligands,
http://linkedlifedata.com/resource/pubmed/chemical/Thiosemicarbazones,
http://linkedlifedata.com/resource/pubmed/chemical/salicylaldehyde
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pubmed:status |
MEDLINE
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pubmed:month |
Jun
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pubmed:issn |
1386-1425
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
70
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
86-93
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pubmed:meshHeading |
pubmed-meshheading:17720619-Aldehydes,
pubmed-meshheading:17720619-Copper,
pubmed-meshheading:17720619-Crystallography, X-Ray,
pubmed-meshheading:17720619-Electron Spin Resonance Spectroscopy,
pubmed-meshheading:17720619-Ligands,
pubmed-meshheading:17720619-Magnetics,
pubmed-meshheading:17720619-Molecular Structure,
pubmed-meshheading:17720619-Spectrophotometry, Infrared,
pubmed-meshheading:17720619-Thiosemicarbazones
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pubmed:year |
2008
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pubmed:articleTitle |
Spectral and structural studies of copper(II) complexes of thiosemicarbazones derived from salicylaldehyde and containing ring incorporated at N(4)-position.
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pubmed:affiliation |
Department of Applied Chemistry, Cochin University of Science and Technology, Kochi 682022, Kerala, India.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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