Linked Life Data

17691726

Source:http://linkedlifedata.com/resource/pubmed/id/17691726

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
18
pubmed:dateCreated
2007-8-27
pubmed:abstractText
Two-electron oxidation of [{Pc(OEt)8}2TbIII]- [Pc(OEt)8=dianion of 2,3,9,10,16,17,23,24-octaethoxyphthalocyanine], which leads to a longitudinal contraction of the coordination space of the single-4f-ionic single-molecule magnet (SMM), resulted in a significant increase of the magnetization-reversal barrier energy and a remarkable upward temperature shift of chi'' peaks and chi'T drops. This is the first evidence that the dynamic magnetism of 4f SMMs can be controlled by a redox reaction on the ligand side without introducing any additional magnetic site or spin system.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Sep
pubmed:issn
0020-1669
pubmed:author
pubmed:issnType
Print
pubmed:day
3
pubmed:volume
46
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
7250-2
pubmed:year
2007
pubmed:articleTitle
Significant increase of the barrier energy for magnetization reversal of a single-4f-ionic single-molecule magnet by a longitudinal contraction of the coordination space.
pubmed:affiliation
Department of Applied Chemistry, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan.
pubmed:publicationType
Journal Article