Linked Life Data

17687480

Source:http://linkedlifedata.com/resource/pubmed/id/17687480

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
31
pubmed:dateCreated
2007-8-9
pubmed:abstractText
Alkyl nitrate yields from the reaction of 1-pentyl, 2-pentyl and 2-methyl-2-butyl peroxy radicals with NO have been determined over the temperature range (261-305 K) and at 1 bar pressure from the photo-oxidation of the iodoalkane precursors in air-NO mixtures. Yields were observed to increase with decreasing temperature and, contrary to previous observations, along the series primary < secondary congruent with tertiary. Our results suggests a significant temperature dependence for the formation of nitrates from the reaction of pentyl peroxy radicals with NO and represent an extension in the temperature range over which this reaction has been studied experimentally in the past.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Aug
pubmed:issn
1463-9076
pubmed:author
pubmed:issnType
Print
pubmed:day
21
pubmed:volume
9
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4332-7
pubmed:meshHeading
pubmed:year
2007
pubmed:articleTitle
Temperature dependence of pentyl nitrate formation from the reaction of pentyl peroxy radicals with NO.
pubmed:affiliation
Centre for Atmospheric Science, University Chemical Laboratory, Lensfield Road, Cambridge, UK. pc254@cam.ac.uk
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't