Source:http://linkedlifedata.com/resource/pubmed/id/17675692
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 8
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| pubmed:dateCreated |
2007-8-6
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| pubmed:abstractText |
Infinite chains connected by N-H...N hydrogen bonding form the primary packing motif in two closely related 4-nitroimidazole derivatives, viz. 5-bromo-2-methyl-4-nitro-1H-imidazole, C(4)H(4)BrN(3)O(2), (I), and 2-methyl-4-nitro-1H-imidazole-5-carbonitrile, C(5)H(4)N(4)O(2), (II). These chains are almost identical, even though in (II) there are two symmetry-independent molecules in the asymmetric unit. The differences appear in the interactions between the chains; in (I), there are strong C-Br...O halogen bonds, which connect the chains into a two-dimensional grid, while in (II), the cyano group does not participate in specific interactions and the chains are only loosely connected into a three-dimensional structure.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Aug
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| pubmed:issn |
0108-2701
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:volume |
63
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
o445-7
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| pubmed:year |
2007
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| pubmed:articleTitle |
Crystal packing of two 5-substituted 2-methyl-4-nitro-1H-imidazoles.
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| pubmed:affiliation |
Nanomaterials Research Centre, and MacDiarmid Institute for Advanced Materials and Nanotechnology, Massey University, Private Bag 11 222, Palmerston North, New Zealand.
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| pubmed:publicationType |
Journal Article
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