Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
12
pubmed:dateCreated
2007-8-6
pubmed:abstractText
This paper outlines the basic events that occur when a semiconductor, in contact with aerated liquid water containing low concentrations of pollutants, is photoexcited. First, the factors favouring this recombination of photoproduced charges are recalled, and the difficulties in decreasing the recombination are underlined. Second, the formation and identification of the species resulting from charge transfer with O2, H2O and pollutants are presented. Third, the reactions involving these species are considered, and methods for assessing their respective importance are critically reviewed. Fourth, on the basis of the view that the photocatalyst surface is covered by tightly bound water layers which hinder the adsorption of many organic pollutants, the hypothesis according to which primary photocatalytic events can take place within the near-surface solution layers is discussed.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:issn
0273-1223
pubmed:author
pubmed:issnType
Print
pubmed:volume
55
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
167-73
pubmed:meshHeading
pubmed:year
2007
pubmed:articleTitle
A brief overview of photocatalytic mechanisms and pathways in water.
pubmed:affiliation
Photocatalyse et Environnement, CNRS, Ecole Centrale de Lyon (STMS), 69134 Ecully CEDEX, France. pichat@ec-lyon.fr
pubmed:publicationType
Journal Article