Source:http://linkedlifedata.com/resource/pubmed/id/17625830
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
16
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| pubmed:dateCreated |
2007-7-30
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| pubmed:abstractText |
Three new chloride-rich zincophosphates including two zero-dimensional (0D) clusters [dl-Co(en)3]2[Zn4(H2PO4)2(HPO4)2Cl8] (denoted ZnPO-CJ33) and [d-Co(en)3]2[Zn4(H2PO4)2(HPO4)2Cl8] (denoted ZnPO-CJ34), and one-dimensional (1D) zincophosphate chain [dl-Co(en)3][Zn2(H2PO4)(HPO4)2Cl2] (denoted ZnPO-CJ35) have been solvothermally prepared. ZnPO-CJ33 and ZnPO-CJ34 possess the same cluster structure as the macroanionic [Zn4H6P4O16Cl8]6- unit formed by alternation of ZnOCl3/ZnO3Cl and HPO4/H2PO4 tetrahedra but differ in the countercations. The racemic [dl-Co(en)3]3+ cations are located among the clusters of ZnPO-CJ33, whereas chiral [d-Co(en)3]3+ cations are located among the clusters of ZnPO-CJ34. ZnPO-CJ34 templated by the optically pure chiral [d-Co(en)3]3+ cations is the first chiral monomeric zincophosphate. ZnPO-CJ35 templated by the racemic [dl-Co(en)3]3+ cations possesses a 1D infinite chain structure formed by the alternation of ZnO3Cl and HPO4/H2PO4 tetrahedra. The 1D chain structure of ZnPO-CJ35 can also be viewed as generated from the condensation of 0D clusters of ZnPO-CJ33, with the terminal Cl ions replaced by HPO4 groups. Experimentally, the structural transformation from ZnPO-CJ33 to ZnPO-CJ35 has been investigated.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Aug
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| pubmed:issn |
0020-1669
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
6
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| pubmed:volume |
46
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
6683-7
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| pubmed:year |
2007
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| pubmed:articleTitle |
Syntheses and characterizations of three low-dimensional chloride-rich zincophosphates assembled about [d-Co(en)(3)](3+) and [dl-Co(en)(3)](3+) complex cations.
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| pubmed:affiliation |
State Key Lab of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, PR China.
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| pubmed:publicationType |
Journal Article
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