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PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
15
pubmed:dateCreated
2007-7-16
pubmed:abstractText
Large-scale uniform dumbbell-like ZnO microcrystals were successfully synthesized via a facile solution method under mild conditions. The as-prepared dumbbells, with lengths of 3.5-5.4 microm and diameters of 1.3-1.8 microm, possess a single-crystal hexagonal structure and grow along the [0001] direction. The influence of the reactant concentration on the size and shapes of the ZnO samples had been studied, and the results revealed that the reactant concentration plays a crucial role in determining final morphologies of the samples. Moreover, the evolution process of the dumbbell-like ZnO microcrystals was viewed by field-emission scanning electron microscopy (FE-SEM) characterization, and a possible formation mechanism was proposed. In addition, optical properties of the ZnO samples prepared at different reaction times were also investigated by photoluminescence (PL) spectroscopy. The room-temperature PL spectrum of the dumbbell-like ZnO microcrystals shows a strong UV emission peak. The UV emission is further identified to originate from the radiative free-exciton recombination by the temperature-dependent PL.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jul
pubmed:issn
0020-1669
pubmed:author
pubmed:issnType
Print
pubmed:day
23
pubmed:volume
46
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
6204-10
pubmed:year
2007
pubmed:articleTitle
Growth of dumbbell-like ZnO microcrystals under mild conditions and their photoluminescence properties.
pubmed:affiliation
National Laboratory of Superhard Materials, Jilin University, Changchun, 130012, P. R. China.
pubmed:publicationType
Journal Article