Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
15
pubmed:dateCreated
2007-7-13
pubmed:abstractText
Reaction of 2-substituted dienamides with catalytic amounts of copper halide/tripyridylamine (TPA) furnishes either 5-exo or 6-endo products with the outcome dependent upon the radical initiating unit. Reaction of 3-substituted dienamides produces beta-lactams via a 4-exo cyclization with termination of the reaction occurring via either halogen atom transfer, trapping with oxygen, elimination, or radical-radical coupling depending upon the diene.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jul
pubmed:issn
0022-3263
pubmed:author
pubmed:issnType
Print
pubmed:day
20
pubmed:volume
72
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
5923-6
pubmed:meshHeading
pubmed:year
2007
pubmed:articleTitle
Regiochemistry of copper(I)-mediated cyclization reactions of halo-dienamides.
pubmed:affiliation
Department of Chemistry, University of Warwick, Coventry, West Midlands, U.K. msrir@csv.warwick.ac.uk
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't