Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
14
pubmed:dateCreated
2007-6-25
pubmed:abstractText
Three methods for the determination of chloramines in water were compared using pH-buffered nanopure water and natural organic matter (NOM) solutions. We investigated whether the N,N-diethyl-p-phenylenediamine (DPD) colorimetric method and/or an adapted indophenol method (Hach MonochlorF) are suitable for determining the concentration of monochloramine in drinking water. Membrane introduction mass spectrometry (MIMS) was used as a reference analysis method to determine the different chloramine species in water. All methods measured monochloramine accurately in Nanopure water, but the DPD colorimetric method measured higher residuals (inorganic and organic chloramines) than MonochlorF or MIMS when in the presence of NOM due to organic chloramines. The indophenol method (MonochlorF) accurately detected only monochloramine and not other chloramine forms. Overall, the monochloramine concentration measured by MonochlorF was comparable with the MIMS results. A combined chlorine residual approach by the DPD colorimetric method does not differentiate between monochloramine and organic chloramines. Therefore, DPD colorimetric methods can overestimate disinfection efficacy in chloraminated water systems because of interference from organic chloramines that have no or poor bactericidal ability. Compared with the DPD colorimetric method, MonochlorF is a better choice for chloraminated water systems.
pubmed:commentsCorrections
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jul
pubmed:issn
0043-1354
pubmed:author
pubmed:issnType
Print
pubmed:volume
41
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
3097-102
pubmed:dateRevised
2007-10-25
pubmed:meshHeading
pubmed:year
2007
pubmed:articleTitle
Comparison of colorimetric and membrane introduction mass spectrometry techniques for chloramine analysis.
pubmed:affiliation
HDR Engineering Inc., 3200 East Camelback Road, Suite 350, Phoenix, AZ 85018, USA. wontae.lee@hdrinc.com
pubmed:publicationType
Journal Article, Comparative Study, Research Support, Non-U.S. Gov't