Source:http://linkedlifedata.com/resource/pubmed/id/17536737
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
6
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| pubmed:dateCreated |
2007-5-31
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| pubmed:abstractText |
A method for rapid speciation analysis of iron was developed by on-line coupling of short column capillary electrophoresis and inductively coupled plasma mass spectrometry. The collision cell technique was used to eliminate argon-based polyatomic interferences and a Micromist nebulizer was employed to increase the nebulization efficiency. Rapid speciation analysis of Fe(II) and Fe(III) was achieved within 1 min by short column capillary electrophoresis in a 14 cm x 50 microm id capillary at 28 kV voltage with a mixture of 15 mmol/L tris(hydroxymethyl)aminomethane + 1 mmol/L 1,10-phenanthroline + 1 mmol/L EDTA (pH 8.6) as running electrolyte. The precisions (RSD, n = 5) of migration time and peak area for Fe(II) and Fe(III) were in the range of 1.0 - 2.6 and 1.9 - 3.9%, respectively. The limits of detection (3sigma) of Fe(II) and Fe(III) were 10.0 and 8.3 microg/L, respectively.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Apr
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| pubmed:issn |
1615-9306
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:volume |
30
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
916-22
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| pubmed:year |
2007
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| pubmed:articleTitle |
Rapid speciation of iron by on-line coupling of short column capillary electrophoresis and inductively coupled plasma mass spectrometry with the collision cell technique.
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| pubmed:affiliation |
Key Laboratory of Functional Polymer Materials, Ministry of Education (Nankai University), Tianjin, China.
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| pubmed:publicationType |
Journal Article
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