Linked Life Data

17535002

Source:http://linkedlifedata.com/resource/pubmed/id/17535002

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
24
pubmed:dateCreated
2007-8-16
pubmed:abstractText
Bottom-up fabrication of 3D organic nanostructures on Si(100) surfaces has been achieved by a two-step procedure. Tetradentate cavitand 1 was grafted on the Si surface together with 1-octene (Oct) as a spatial spectator by photochemical hydrosilylation. Ligand exchange between grafted cavitand 1 and self-assembled homocage 2, derived from cavitand 5 bearing a fluorescence marker, led to the formation of coordination cages on Si(100). Formation, quantification, and distribution of the nanoscale molecular containers on a silicon surface was assessed by using three complementary analytical techniques (AFM, XPS, and fluorescence) and validated by control experiments on cavitand-free silicon surfaces. Interestingly, the fluorescence of pyrene at approximately 4 nm above the Si(100) surface can be clearly observed.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:issn
0947-6539
pubmed:author
pubmed:issnType
Print
pubmed:volume
13
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
6891-8
pubmed:dateRevised
2009-8-4
pubmed:year
2007
pubmed:articleTitle
Self-assembly of nanosize coordination cages on si(100) surfaces.
pubmed:affiliation
Dipartimento di Chimica Organica ed Industriale University of Parma and INSTM UdR Parma V.le G. P. Usberti 17 A, 43100 Parma, Italy.
pubmed:publicationType
Journal Article