Source:http://linkedlifedata.com/resource/pubmed/id/17439207
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
10
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pubmed:dateCreated |
2007-5-7
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pubmed:abstractText |
The first imine-bridged pyridyltetrathiafulvalene building block (TTF-CH=N-Py, 1) has been synthesized via the Schiff base condensation of formyltetrathiafulvalene and 2-aminopyridine. The preparation, X-ray crystal structure, electrochemical and magnetic characterization of a 1:1 copper complex [CuII(hfac)2(TTF-CH=N-Py)] (2) are reported. The crystal structure reveals that the imine N atom participates in chelation to the paramagnetic center, thus making this ligand an attractive precursor for the assembly of pi-d systems.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
May
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pubmed:issn |
0020-1669
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
14
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pubmed:volume |
46
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
3807-9
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pubmed:year |
2007
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pubmed:articleTitle |
Preparation and coordination complex of the first imine-bridged tetrathiafulvalene-pyridine donor ligand.
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pubmed:affiliation |
Department of Chemistry, Brock University, 500 Glenridge Avenue, St. Catharines, L2S 3A1 Ontario, Canada.
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pubmed:publicationType |
Journal Article
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