Source:http://linkedlifedata.com/resource/pubmed/id/17413222
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 4
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| pubmed:dateCreated |
2007-4-6
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| pubmed:abstractText |
The reaction of bis(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)(2)], with bis(diphenylphosphino)ethane (dppe) affords the coordination polymer catena-poly[[bis(1,3-diphenylpropane-1,3-dionato-kappa(2)O,O')cobalt(II)]-mu-ethylenebis(diphenylphosphine oxide)-kappa(2)O:O'], trans-[Co(C(15)H(11)O(2))(2)(C(26)H(24)O(2)P(2))](n), as a result of oxidation of the diphosphine. The Co atom is octahedral, with a CoO(6) coordination sphere, and the chelating dbm ligands adopt a trans configuration. The Co atom also lies on a centre of inversion, with a further symmetry centre bisecting the bridging ethylenebis(diphenylphosphine oxide) ligand.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Apr
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| pubmed:issn |
0108-2701
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:volume |
63
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m163-5
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| pubmed:year |
2007
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| pubmed:articleTitle |
Unexpected oxidation of a diphosphine by bis(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)2].
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| pubmed:affiliation |
Department of Chemistry, School of Science, Walailak University, Thasala, Nakhon Si Thammarat 80161, Thailand. hdavid@wu.ac.th
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| pubmed:publicationType |
Journal Article
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