Source:http://linkedlifedata.com/resource/pubmed/id/17407353
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
9
|
| pubmed:dateCreated |
2007-4-20
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| pubmed:abstractText |
Optically active N-sulfinimines underwent stereoselective Michael/nucleophilic addition domino reaction triggered by magnesium thiolate to give alpha-phenylthiomethyl-beta-(N-sulfinylamino) esters in high diastereomeric excess. The adducts were readily converted into optically active alpha-methylene-beta-(N-sulfinylamino)esters so that this reaction provides a useful asymmetric aza-Baylis-Hillman-equivalent method.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:citationSubset |
IM
|
| pubmed:chemical | |
| pubmed:status |
MEDLINE
|
| pubmed:month |
Apr
|
| pubmed:issn |
0022-3263
|
| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
27
|
| pubmed:volume |
72
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
3569-72
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| pubmed:meshHeading |
pubmed-meshheading:17407353-Chemistry, Organic,
pubmed-meshheading:17407353-Crystallography, X-Ray,
pubmed-meshheading:17407353-Imines,
pubmed-meshheading:17407353-Molecular Structure,
pubmed-meshheading:17407353-Stereoisomerism,
pubmed-meshheading:17407353-Sulfinic Acids,
pubmed-meshheading:17407353-Sulfur,
pubmed-meshheading:17407353-beta-Lactams
|
| pubmed:year |
2007
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| pubmed:articleTitle |
Asymmetric thio-Michael/nucleophilic addition domino reaction with chiral N-sulfinimines.
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| pubmed:affiliation |
Department of Applied Molecular Bioscience, Graduate School of Medicine, Yamaguchi University, Ube 755-8611, Japan. ak10@yamaguchi-u.ac.jp
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| pubmed:publicationType |
Journal Article
|