17312979

Source:http://linkedlifedata.com/resource/pubmed/id/17312979

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0175921, umls-concept:C0401925, umls-concept:C1704675, umls-concept:C1707691
pubmed:issue	22
pubmed:dateCreated	2007-2-22
pubmed:abstractText	The conformational properties and the stability of acylpyridinium intermediates formed in pyridine-catalyzed acylation reactions have been studied at the SCS-MP2(FC)/6-311 +G(d,p)//MP2(FC)/ 6-31G(d) level of theory. It has been shown that stacking interactions can play a decisive role in the stability as well as the conformational preferences of these transient intermediates.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/101154995
pubmed:citationSubset	IM
pubmed:chemical	http://linkedlifedata.com/resource/pubmed/chemical/Pyridines
pubmed:status	MEDLINE
pubmed:month	Nov
pubmed:issn	1477-0520
pubmed:author	pubmed-author:AiMM, pubmed-author:HeldIngmarI, pubmed-author:ZipseHendrikH
pubmed:issnType	Print
pubmed:day	21
pubmed:volume	4
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	4223-30
pubmed:meshHeading	pubmed-meshheading:17312979-Acylation, pubmed-meshheading:17312979-Catalysis, pubmed-meshheading:17312979-Models, Chemical, pubmed-meshheading:17312979-Models, Molecular, pubmed-meshheading:17312979-Molecular Structure, pubmed-meshheading:17312979-Pyridines
pubmed:year	2006
pubmed:articleTitle	Stacking interactions as the principal design element in acyl-transfer catalysts.
pubmed:affiliation	Department Chemie und Biochemie, LMU München, Butenandtstrasse 5-13, D-81377, München, Germany.
pubmed:publicationType	Journal Article, Research Support, Non-U.S. Gov't