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rdf:type |
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lifeskim:mentions |
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pubmed:issue |
3
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pubmed:dateCreated |
2007-1-26
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pubmed:abstractText |
Aldimines derived from aryl and non-enolizable aliphatic aldehydes were allylated with allyl bromide mediated by indium powder in [bpy][BF4] (bpy = N-butylpyridine) to give good yields of the corresponding homoallylic amines. Selective formation of monoallylated amines can be achieved by varying the amount of bromide ion additive in the form of [bpy][Br]. The transient organoindium intermediates, allylindium(I) and allylindium(III) dibromide formed in the reaction, were studied by NMR spectroscopy to explain the selectivity.
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
Feb
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pubmed:issn |
0022-3263
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pubmed:author |
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pubmed:issnType |
Print
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pubmed:day |
2
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pubmed:volume |
72
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
923-9
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pubmed:meshHeading |
pubmed-meshheading:17253812-Allyl Compounds,
pubmed-meshheading:17253812-Amines,
pubmed-meshheading:17253812-Catalysis,
pubmed-meshheading:17253812-Hydrocarbons, Brominated,
pubmed-meshheading:17253812-Imines,
pubmed-meshheading:17253812-Indium,
pubmed-meshheading:17253812-Ionic Liquids,
pubmed-meshheading:17253812-Magnetic Resonance Spectroscopy,
pubmed-meshheading:17253812-Molecular Structure,
pubmed-meshheading:17253812-Organometallic Compounds
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pubmed:year |
2007
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pubmed:articleTitle |
Synthetic and mechanistic studies of indium-mediated allylation of imines in ionic liquids.
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pubmed:affiliation |
Department of Chemistry, McGill University, Montreal, Quebec, Canada H3A 2K6.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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