17252128

Source:http://linkedlifedata.com/resource/pubmed/id/17252128

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0010558, umls-concept:C0023688, umls-concept:C0220781, umls-concept:C1100802, umls-concept:C1706853, umls-concept:C1879748, umls-concept:C1883254
pubmed:issue	3
pubmed:dateCreated	2007-1-25
pubmed:abstractText	Cyclodextrin [2] and [3]rotaxanes have been synthesised by use of a metal-driven ligand formation methodology. The kinetically stable cobalt(III) complexes formed act as either linking or capping groups, the function being selected by manipulation of the reaction conditions to promote the formation of either 2:1 or 1:1 complexes, respectively. In all cases, mixtures of isomers containing different alpha-cyclodextrin orientations were observed. All three orientational isomers of the [3]rotaxane were isolated and structurally characterized by 2D NMR.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/101154995
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Feb
pubmed:issn	1477-0520
pubmed:author	pubmed-author:AndersonHarry LHL, pubmed-author:CheethamAndrew GAG, pubmed-author:ClaridgeTimothy D WTD
pubmed:issnType	Print
pubmed:day	7
pubmed:volume	5
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	457-62
pubmed:year	2007
pubmed:articleTitle	Metal-driven ligand assembly in the synthesis of cyclodextrin [2] and [3]rotaxanes.
pubmed:affiliation	Department of Chemistry, Chemistry Research Laboratory, University of Oxford, 12 Mansfield Rd, Oxford, UK OX1 3TA.
pubmed:publicationType	Journal Article