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rdf:type |
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lifeskim:mentions |
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pubmed:issue |
1
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pubmed:dateCreated |
2006-12-12
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pubmed:abstractText |
The complex cations [RuL2(H2biim)]2+ (L=bipy, 4,4'-tBu2-bipy) interact with cyanometallate anions via a chelating hydrogen-bonding interaction between the two N-H donors of the complex cation and the N lone pair of one cyanide ligand in the complex anion; the anion hexacyanoferrate(III) quenches the Ru(II)-based luminescence in CH2Cl2 solution by photoinduced electron-transfer within the H-bonded assembly, whereas hexacyanocobaltate(III) enhances the Ru(II)-based luminescence.
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pubmed:commentsCorrections |
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
Jan
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pubmed:issn |
1477-9226
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pubmed:author |
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pubmed:issnType |
Print
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pubmed:day |
7
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
33-6
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pubmed:meshHeading |
pubmed-meshheading:17160171-Anions,
pubmed-meshheading:17160171-Cations,
pubmed-meshheading:17160171-Hydrogen Bonding,
pubmed-meshheading:17160171-Imidazoles,
pubmed-meshheading:17160171-Ligands,
pubmed-meshheading:17160171-Luminescence,
pubmed-meshheading:17160171-Luminescent Measurements,
pubmed-meshheading:17160171-Magnetic Resonance Spectroscopy,
pubmed-meshheading:17160171-Models, Molecular,
pubmed-meshheading:17160171-Nitriles,
pubmed-meshheading:17160171-Organometallic Compounds,
pubmed-meshheading:17160171-Photochemistry,
pubmed-meshheading:17160171-Ruthenium,
pubmed-meshheading:17160171-Sensitivity and Specificity
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pubmed:year |
2007
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pubmed:articleTitle |
Hydrogen-bonded assemblies of ruthenium(II)-biimidazole complex cations and cyanometallate anions: structures and photophysics.
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pubmed:affiliation |
Department of Chemistry, University of Sheffield, Sheffield, UK S3 7HF.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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