Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
11
pubmed:dateCreated
2007-1-15
pubmed:abstractText
Hydrogen titanate (H-titanate) nanowires were prepared via a hydrothermal reaction of TiO2 powders (P25) in KOH solutions and then calcined at various temperatures. The phase structure, crystallite size, morphology, specific surface area, and pore structures of the calcined H-titanate nanowires at various temperatures were characterized with field emission scanning electron microscope, X-ray diffraction, transmission electron microscopy and nitrogen adsorption-desorption isotherms, and their photocatalytic activities were evaluated by photocatalytic oxidation of acetone in air. With increasing calcination temperature, the specific surface area and porosity of the calcined samples steadily decreased. At a calcination temperature range of 400-600 degrees C, the calcined H-titanate nanowires showed higher photocatalytic activity than P25 powders for photocatalytic oxidation of acetone. Especially, at 500 degrees C, the calcined H-titanate nanowires showed the highest photocatalytic activity, which exceeded that of P25 by a factor of about 1.8 times. This can be attributed to the synergetic effect of larger specific surface area, higher pore volume and the presence of brookite TiO2. With further increase in the calcination temperature (700-900 degrees C), the photocatalytic activity of the samples decreased obviously owing to the growth of TiO2 crystallites.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Feb
pubmed:issn
0045-6535
pubmed:author
pubmed:issnType
Print
pubmed:volume
66
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2050-7
pubmed:meshHeading
pubmed:year
2007
pubmed:articleTitle
Photocatalytic activity of the calcined H-titanate nanowires for photocatalytic oxidation of acetone in air.
pubmed:affiliation
State Key Laboratory of Advanced Technology for Material Synthesis and Processing, Wuhan University of Technology, Luoshi Road 122#, Wuhan 430070, PR China.
pubmed:publicationType
Journal Article, Comparative Study, Research Support, Non-U.S. Gov't