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rdf:type |
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lifeskim:mentions |
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pubmed:issue |
3-4
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pubmed:dateCreated |
2007-2-2
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pubmed:abstractText |
The direct oxidation of UDP-alpha-d-glucose and UDP-N-acetyl-alpha-d-glucosamine to the corresponding uronic acids was explored using either TEMPO or platinum-catalysed oxidation with molecular oxygen. Whilst TEMPO-based procedures gave rise to substantial over-oxidation and/or degradation of UDP-glucose, oxidation of UDP-N-acetyl-glucosamine to UDP-N-acetyl-glucosaminuronic acid was achieved with >90% conversion and ca. 65% isolated yield using a platinum-catalysed procedure.
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Cyclic N-Oxides,
http://linkedlifedata.com/resource/pubmed/chemical/Nucleoside Diphosphate Sugars,
http://linkedlifedata.com/resource/pubmed/chemical/Platinum,
http://linkedlifedata.com/resource/pubmed/chemical/TEMPO,
http://linkedlifedata.com/resource/pubmed/chemical/UDP-N-acetylglucosaminuronic acid,
http://linkedlifedata.com/resource/pubmed/chemical/Uridine Diphosphate,
http://linkedlifedata.com/resource/pubmed/chemical/Uridine Diphosphate Glucose,
http://linkedlifedata.com/resource/pubmed/chemical/Uridine Diphosphate Glucuronic Acid,
http://linkedlifedata.com/resource/pubmed/chemical/Uridine Diphosphate...,
http://linkedlifedata.com/resource/pubmed/chemical/Uridine Diphosphate Sugars,
http://linkedlifedata.com/resource/pubmed/chemical/Uronic Acids
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pubmed:status |
MEDLINE
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pubmed:month |
Feb
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pubmed:issn |
0008-6215
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pubmed:author |
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pubmed:issnType |
Print
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pubmed:day |
26
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pubmed:volume |
342
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
460-6
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pubmed:dateRevised |
2008-9-9
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pubmed:meshHeading |
pubmed-meshheading:17087923-Catalysis,
pubmed-meshheading:17087923-Cyclic N-Oxides,
pubmed-meshheading:17087923-Nucleoside Diphosphate Sugars,
pubmed-meshheading:17087923-Oxidation-Reduction,
pubmed-meshheading:17087923-Platinum,
pubmed-meshheading:17087923-Uridine Diphosphate,
pubmed-meshheading:17087923-Uridine Diphosphate Glucose,
pubmed-meshheading:17087923-Uridine Diphosphate Glucuronic Acid,
pubmed-meshheading:17087923-Uridine Diphosphate N-Acetylglucosamine,
pubmed-meshheading:17087923-Uridine Diphosphate Sugars,
pubmed-meshheading:17087923-Uronic Acids
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pubmed:year |
2007
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pubmed:articleTitle |
Direct oxidation of sugar nucleotides to the corresponding uronic acids: TEMPO and platinum-based procedures.
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pubmed:affiliation |
Centre for Carbohydrate Chemistry, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich NR4 7TJ, UK.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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