Linked Life Data

17083241

Source:http://linkedlifedata.com/resource/pubmed/id/17083241

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
23
pubmed:dateCreated
2006-11-6
pubmed:abstractText
The synthesis and photophysical study of (C/\N)Pt(II)Q complexes, where C/\N is a bidentate cyclometalating ligand and Q is 8-hydroxyquinoline or quinoline-8-thiol, are presented. The compounds were obtained as a single isomer with N atoms of the C/\N and Q ligands trans-coordinated to the Pt(II) center as shown by X-ray crystallography. These chromophores absorb intensely in the visible region and emit in the deep-red spectral region from a quinolate-centered triplet intraligand charge-transfer excited state. The emission maxima are in the range 675-740 nm, with the quantum yields and lifetimes of up to 0.82% and 5.3 mus, respectively, in deoxygenated organic solvents at room temperature. These complexes are efficient photosensitizers of singlet oxygen in air-saturated solutions, with yields up to 90%.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Nov
pubmed:issn
0020-1669
pubmed:author
pubmed:issnType
Print
pubmed:day
13
pubmed:volume
45
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
9410-5
pubmed:year
2006
pubmed:articleTitle
Deep-red luminescence and efficient singlet oxygen generation by cyclometalated platinum(II) complexes with 8-hydroxyquinolines and quinoline-8-thiol.
pubmed:affiliation
Department of Chemistry, University of Sheffield, Sheffield S3 7HF, United Kingdom.
pubmed:publicationType
Journal Article