Linked Life Data

17083222

Source:http://linkedlifedata.com/resource/pubmed/id/17083222

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
23
pubmed:dateCreated
2006-11-6
pubmed:abstractText
A highly luminescent novel cationic iridium complex [iridium bis(2-phenylpyridine)(4,4'-(dimethylamino)-2,2'-bipyridine)]PF6 was synthesized and characterized using NMR, UV-visible absorption, and emission spectroscopy and electrochemical methods. This complex displays intense photoluminescence maxima in the green-blue region of the visible spectrum and exhibits unprecedented phosphorescence quantum yields, 80 +/- 10% with an excited-state lifetime of 2.2 mus in a dichloromethane solution at 298 K. Single-layer light-emitting electrochemical cells with the charged complex as conducting and electroluminescent material sandwiched between indium-tin oxide and Ag electrodes were fabricated, which emit green-blue light with an onset voltage as low as 2.5 V. Density functional theory calculations were performed to provide insight into the electronic structure of the [iridium bis(2-phenylpyridine)(4,4'-(dimethylamino)-2,2'-bipyridine)]PF6 complex, comparing these results with those obtained for [iridium bis(2-phenylpyridine)(4,4'-tert-butyl-2,2'-bipyridine)]PF6.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Nov
pubmed:issn
0020-1669
pubmed:author
pubmed:issnType
Print
pubmed:day
13
pubmed:volume
45
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
9245-50
pubmed:year
2006
pubmed:articleTitle
Efficient green-blue-light-emitting cationic iridium complex for light-emitting electrochemical cells.
pubmed:affiliation
Laboratory for Photonics and Interfaces, Institute of Chemical Sciences and Engineering, School of basic Sciences, Swiss Federal Institute of Technology, CH-1015 Lausanne, Switzerland. MdKhaja.Nazeeruddin@epfl.ch
pubmed:publicationType
Journal Article