Source:http://linkedlifedata.com/resource/pubmed/id/17081022
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
23
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| pubmed:dateCreated |
2006-11-3
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| pubmed:abstractText |
Methanol is converted to a mixture of hydrocarbons by reaction with zinc iodide at 200 degrees C with one highly branched alkane, 2,2,3-trimethylbutane (triptane), being obtained in surprisingly high selectivity. Mechanistic studies implicate a two-stage process, the first involving heterogeneously catalyzed formation of a carbon-carbon-bonded species, probably ethylene, that undergoes homogeneously catalyzed sequential cationic methylation to higher hydrocarbons. The first stage can be bypassed by addition of olefins, higher alcohols, or arenes, which act as initiators. Rationales for the particular activity of zinc iodide and for the selectivity to triptane are proposed.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Nov
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| pubmed:issn |
0022-3263
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| pubmed:author |
pubmed-author:BercawJohn EJE,
pubmed-author:DiaconescuPaula LPL,
pubmed-author:GrubbsRobert HRH,
pubmed-author:KaoRichard JRJ,
pubmed-author:KitchingSarahS,
pubmed-author:LabingerJay AJA,
pubmed-author:LiXingweiX,
pubmed-author:MehrkhodavandiParisaP,
pubmed-author:MorrisGeorge EGE,
pubmed-author:SunleyGlenn JGJ,
pubmed-author:VagnerPatrickP
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| pubmed:issnType |
Print
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| pubmed:day |
10
|
| pubmed:volume |
71
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
8907-17
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| pubmed:year |
2006
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| pubmed:articleTitle |
On the mechanism of the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide.
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| pubmed:affiliation |
Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA.
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| pubmed:publicationType |
Journal Article
|