Source:http://linkedlifedata.com/resource/pubmed/id/17064019
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
22
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pubmed:dateCreated |
2006-10-26
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pubmed:abstractText |
2-Iodylphenol ethers were prepared by the dimethyldioxirane oxidation of the corresponding 2-iodophenol ethers and isolated as chemically stable, microcrystalline products. Single-crystal X-ray diffraction analysis of 1-iodyl-2-isopropoxybenzene 8c and 1-iodyl-2-butoxybenzene 8d revealed pseudopolymeric arrangements in the solid state formed by intermolecular interactions between IO2 groups of different molecules. 2-Iodylphenol ethers can selectively oxidize sulfides to sulfoxides and alcohols to the respective aldehydes or ketones.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Oct
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pubmed:issn |
0022-3263
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
27
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pubmed:volume |
71
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
8452-8
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pubmed:year |
2006
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pubmed:articleTitle |
2-iodylphenol ethers: preparation, X-ray crystal structure, and reactivity of new hypervalent iodine(V) oxidizing reagents.
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pubmed:affiliation |
Department of Chemistry and Biochemistry, University of Minnesota--Duluth, Duluth, Minnesota 55812, USA.
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pubmed:publicationType |
Journal Article
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