Linked Life Data

17048877

Source:http://linkedlifedata.com/resource/pubmed/id/17048877

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
42
pubmed:dateCreated
2006-10-19
pubmed:abstractText
Design of nanohybrid systems possessing several ruthenium trisbipyridine (Ru(bpy)(3)(2+)) chromophores on the surface of gold nanoparticles, by adopting a place exchange reaction, was reported and their photophysical properties were tuned by varying the density of chromophores. The charge shift between the excited and ground-state Ru(bpy)(3)(2+) chromophores was reported for the first time, leading to the formation of Ru(bpy)(3)(+) and Ru(bpy)(3)(3+). Electron-transfer products were not observed on decreasing the concentration of Ru(bpy)(3)(2+) functionalized on Au nanoparticles or in a saturated solution of unbound chromophores. The close proximity of the chromophores on periphery of the gold core may lead to an electron transfer reaction and the products sustained for several nanoseconds before undergoing recombination, probably due to the stabilizing effect of the polar ethylene glycol moieties embedded between the chromophore groups.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Oct
pubmed:issn
1520-6106
pubmed:author
pubmed:issnType
Print
pubmed:day
26
pubmed:volume
110
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
20737-41
pubmed:meshHeading
pubmed:year
2006
pubmed:articleTitle
Photochemistry of ruthenium trisbipyridine functionalized on gold nanoparticles.
pubmed:publicationType
Letter, Research Support, U.S. Gov't, Non-P.H.S., Research Support, Non-U.S. Gov't