17048839

Source:http://linkedlifedata.com/resource/pubmed/id/17048839

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0016850, umls-concept:C0205250, umls-concept:C0220841, umls-concept:C0443286
pubmed:issue	22
pubmed:dateCreated	2006-10-19
pubmed:abstractText	The Friedel-Crafts reaction of (1R)-8-phenylmenthyl glyoxylate with variously substituted furans was found to be efficiently promoted by SnCl(4) or magnesium salts with high diastereoselectivities. MgBr(2) performs especially well under simple, undemanding conditions, giving both high yields and high diastereoselectivities (>90%). The reaction afforded chiral substituted furan-2-yl-hydroxyacetic acid esters, compounds of potentially high synthetic interest. [reaction: see text]
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Oct
pubmed:issn	1523-7060
pubmed:author	pubmed-author:Cha?adajWojciechW, pubmed-author:JurczakJanuszJ, pubmed-author:KwiatkowskiPiotrP, pubmed-author:MajerJakubJ
pubmed:issnType	Print
pubmed:day	26
pubmed:volume	8
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	5045-8
pubmed:year	2006
pubmed:articleTitle	Highly diastereoselective Friedel-Crafts reaction of furans with 8-phenylmenthyl glyoxylate.
pubmed:affiliation	Institute of Organic Chemistry, Polish Academy of Sciences, 01-224 Warsaw, Poland.
pubmed:publicationType	Journal Article