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PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
37
pubmed:dateCreated
2006-9-14
pubmed:abstractText
We report a simple solution route to large-scale synthesis of uniform, single-crystalline, and well-faceted orthorhombic antimony trioxide (Sb(2)O(3)) nanowires with rectangular cross sections by direct air oxidation of bulk metal antimony (Sb) in a mixed solution made of ethylenediamine (EDA) and deionized water (DIW). The as-synthesized products were analyzed by range of methods, such as XRD, SEM, EDX, TEM, SAED, HRTEM, FTIR, Raman, UV-vis absorption, and photoluminescence (PL) spectra. The as-synthesized Sb(2)O(3) nanowires with rectangular cross sections are usually hundreds of micrometers in length, typically 80-100 nm in width, and 60-80 nm in thickness. The novel room temperature photoluminescence properties of Sb(2)O(3) nanowires with rectangular cross sections displayed a significant UV luminescence with a strong emission band at 374 nm, which was reported for the first time, indicating the as-synthesized products with an optical band gap E(g) = 3.3 eV. It is expected that as-synthesized Sb(2)O(3) nanowires would be a new member of functional materials and used in the manufacture of advanced nanodevices.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Sep
pubmed:issn
1520-6106
pubmed:author
pubmed:issnType
Print
pubmed:day
21
pubmed:volume
110
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
18225-30
pubmed:meshHeading
pubmed:year
2006
pubmed:articleTitle
A simple solution route to single-crystalline Sb2O3 nanowires with rectangular cross sections.
pubmed:affiliation
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't