Source:http://linkedlifedata.com/resource/pubmed/id/16946066
Switch to
| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
5791
|
| pubmed:dateCreated |
2006-9-1
|
| pubmed:abstractText |
Vanadium phosphates are important catalysts for the oxidation of alkanes, and commercial catalysts comprise a complex range of V4+ and V5+ phosphates. We used three complementary in situ characterization methodologies-powder x-ray diffraction and laser Raman and electron paramagnetic resonance spectroscopies-to show that the metastable phase omega-VOPO4 is very sensitive to many of the reactants and products of butane oxidation. A rapid transformation from omega-VOPO4 to delta-VOPO4 occurs on exposure to butane at the reaction temperature, and hence the metastable omega-VOPO4 may play a role in the formation of commercial catalysts.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Sep
|
| pubmed:issn |
1095-9203
|
| pubmed:author |
pubmed-author:BartleyJonathan KJK,
pubmed-author:BudroniGerolamoG,
pubmed-author:CarleyAlbert FAF,
pubmed-author:ConteMarcoM,
pubmed-author:GirgsdiesFrankF,
pubmed-author:HutchingsGraham JGJ,
pubmed-author:MurphyDamien MDM,
pubmed-author:ResslerThorstenT,
pubmed-author:SchlöglRobertR,
pubmed-author:SchmidtAndiA,
pubmed-author:TaylorStuart HSH
|
| pubmed:issnType |
Electronic
|
| pubmed:day |
1
|
| pubmed:volume |
313
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
1270-3
|
| pubmed:dateRevised |
2007-3-19
|
| pubmed:year |
2006
|
| pubmed:articleTitle |
Chemically induced fast solid-state transitions of omega-VOPO4 in vanadium phosphate catalysts.
|
| pubmed:affiliation |
School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK.
|
| pubmed:publicationType |
Journal Article
|