Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
33
pubmed:dateCreated
2006-8-17
pubmed:abstractText
A coordination compound of HgI(2)(pyridine)(2) can be successfully intercalated into a single crystalline Bi(2)Sr(2)CaCu(2)O(y) high-T(c) superconductor through an interlayer complexation reaction between pyridine molecules and bismuth cuprate pre-intercalated with mercuric iodide. X-ray diffraction and X-ray absorption spectroscopic results clearly demonstrate that the single crystalline nature of the pristine bismuth cuprate remains unchanged even after the intercalation of organic complex as well as those of iodine and mercuric iodide. According to the angle-dependent dc magnetization measurements, the intercalation of bulky organic molecules completely blocks superconductive currents along the c-axis, whereas a superconducting transition along the in-plane direction still occurs in the organic intercalate. In the case of the iodine or mercuric iodide intercalates with smaller lattice expansions, an out-of-plane diamagnetic transition is not wholly quenched but significantly depressed by the intercalation, confirming the reduction of interlayer interaction. The present finding can provide straightforward evidence of the two-dimensionality of high temperature superconductivity in the present cuprate-based nanohybrid material.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Aug
pubmed:issn
1520-6106
pubmed:author
pubmed:issnType
Print
pubmed:day
24
pubmed:volume
110
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
16197-200
pubmed:meshHeading
pubmed:year
2006
pubmed:articleTitle
Evidence of two-dimensional superconductivity in the single crystalline nanohybrid of organic-bismuth cuprate.
pubmed:publicationType
Letter, Research Support, Non-U.S. Gov't